Publications from 2019

Computing the electronic structure of molecules with high precision is a central challenge in the field of quantum chemistry. Despite the enormous success of approximate methods, tackling this problem exactly with conventional computers is still a formidable task. This has triggered several theoretical and experimental efforts to use quantum computers to solve chemistry problems, with first proof-of-principle realizations done in a digital manner. An appealing alternative to the digital approach is analog quantum simulation, which does not require a scalable quantum computer, and has already been successfully applied in condensed matter physics problems. However, all available or planned setups cannot be used in quantum chemistry problems, since it is not known how to engineer the required Coulomb interactions with them. Here, we present a new approach to the simulation of quantum chemistry problems in an analog way. Our method relies on the careful combination of two technologies: ultra-cold atoms in optical lattices and cavity QED. In the proposed simulator, fermionic atoms hopping in an optical potential play the role of electrons, additional optical potentials provide the nuclear attraction, and a single spin excitation over a Mott insulator mediates the electronic Coulomb repulsion with the help of a cavity mode. We also provide the operational conditions of the simulator and benchmark it with a simple molecule. Our work opens up the possibility of efficiently computing electronic structures of molecules with analog quantum simulation.

The possibility of creating crystal bilayers twisted with respect to each other has led to the discovery of a wide range of novel electron correlated phenomena whose full understanding is still under debate. Here we propose and analyze a method to simulate twisted bilayers using cold atoms in state-dependent optical lattices. Our proposed setup can be used as an alternative platform to explore twisted bilayers which allows one to control the inter/intra-layer coupling in a more flexible way than in the solid-state realizations. We focus on square geometries but also point how it can be extended to simulate other lattices which show Dirac-like physics. This setup opens a path to observe similar physics, e.g., band narrowing, with larger twist angles, to rule out some of the mechanisms to explain the observed strongly correlated effects, as well as to study other phenomena difficult to realize with crystals. As an example of the latter we explore the quantum optical consequences of letting emitters interact with twisted bilayer reservoirs, and predict the appearance of unconventional radiation patterns and emitter interactions following the emergent Moir\’e geometry.

Emitters coupled simultaneously to distant positions of a photonic bath, the so-called giant atoms, represent a new paradigm in quantum optics. When coupled to one-dimensional baths, as recently implemented with transmission lines or SAW waveguides, they lead to striking effects such as chiral emission or decoherence-free atomic interactions. Here, we show how to create giant atoms in dynamical state-dependent optical lattices, which offers the possibility of coupling them to structured baths in arbitrary dimensions. This opens up new avenues to a variety of phenomena and opportunities for quantum simulation. In particular, we show how to engineer unconventional radiation patterns, like multi-directional chiral emission, as well as collective interactions that can be used to simulate non-equilibrium many-body dynamics with no analogue in other setups. Besides, the recipes we provide to harness giant atoms in high dimensions can be exported to other platforms where such non-local couplings can be engineered.

We develop energy efficient, continuous microwave schemes to couple electron and nuclear spins, using phase or amplitude modulation to bridge their frequency difference. These controls have promising applications in biological systems, where microwave power should be limited, as well as in situations with high Larmor frequencies due to large magnetic fields and nuclear magnetic moments. These include nanoscale NMR where high magnetic fields achieves enhanced thermal nuclear polarisation and larger chemical shifts. Our controls are also suitable for quantum information processors and nuclear polarisation schemes.

In this work, we study the driven-dissipative dynamics of a coherently-driven spin ensemble with a squeezed, superradiant decay. This decay consists of a sum of both raising and lowering collective spin operators with a tunable weight. The model presents different critical non-equilibrium phases with a gapless Liouvillian that are associated to particular symmetries and that give rise to distinct kinds of non-ergodic dynamics. In Ref. [1] we focus on the case of a strong-symmetry and use this model to introduce and discuss the effect of dissipative freezing, where, regardless of the system size, stochastic quantum trajectories initialized in a superposition of different symmetry sectors always select a single one of them and remain there for the rest of the evolution. Here, we deepen this analysis and study in more detail the other type of non-ergodic physics present in the model, namely, the emergence of non-stationary dynamics in the thermodynamic limit. We complete our description of squeezed superradiance by analysing its metrological properties in terms of spin squeezing and by analysing the features that each of these critical phases imprint on the light emitted by the system.

Photonic states with large and fixed photon numbers, such as Fock states, enable quantum-enhanced metrology but remain an experimentally elusive resource. A potentially simple, deterministic and scalable way to generate these states consists of fully exciting $N$ quantum emitters equally coupled to a common photonic reservoir, which leads to a collective decay known as Dicke superradiance. The emitted $N$-photon state turns out to be a highly entangled multimode state, and to characterise its metrological properties in this work we: (i) develop theoretical tools to compute the Quantum Fisher Information of general multimode photonic states; (ii) use it to show that Dicke superradiant photons in 1D waveguides achieve Heisenberg scaling, which can be saturated by a parity measurement; (iii) and study the robustness of these states to experimental limitations in state-of-art atom-waveguide QED setups.

Heisenberg’s uncertainty principle implies that the quantum vacuum is not empty but fluctuates. These fluctuations can be converted into radiation through nonadiabatic changes in the Hamiltonian. Here, we discuss how to control this vacuum radiation, engineering a single-photon emitter out of a two-level system (2LS) ultrastrongly coupled to a finite-band waveguide in a vacuum state. More precisely, we show the 2LS nonlinearity shapes the vacuum radiation into a nonGaussian superposition of even and odd cat states. When the 2LS bare frequency lays within the band gaps, this emission can be well approximated by individual photons. This picture is confirmed by a characterization of the ground and bound states, and a study of the dynamics with matrix product states and polaron Hamiltonian methods.

In driven-dissipative systems, the presence of a strong symmetry guarantees the existence of several steady states belonging to different symmetry sectors. Here we show that, when a system with a strong symmetry is initialized in a quantum superposition involving several of these sectors, each individual stochastic trajectory will randomly select a single one of them and remain there for the rest of the evolution. Since a strong symmetry implies a conservation law for the corresponding symmetry operator on the ensemble level, this selection of a single sector from an initial superposition entails a breakdown of this conservation law at the level of individual realizations. Given that such a superposition is impossible in a classical, stochastic trajectory, this is a a purely quantum effect with no classical analogue. Our results show that a system with a closed Liouvillian gap may exhibit, when monitored over a single run of an experiment, a behaviour completely opposite to the usual notion of dynamical phase coexistence and intermittency, which are typically considered hallmarks of a dissipative phase transition. We discuss our results with a simple, realistic model of squeezed superradiance.

We present a characterization of topological phases in photonic lattices. Our theory relies on a formal equivalence between the singular value decomposition of the non-Hermitian coupling matrix and the diagonalization of an effective Hamiltonian. By means of that mapping we unveil an application of topological band theory to the description of quantum amplification with non-reciprocal systems. We exemplify our ideas with an array of photonic cavities which can be mapped into a topological insulator Hamiltonian in the AIII symmetry class. We investigate stability properties and prove the existence of stable topologically non-trivial steady-state phases. Finally, we show numerically that the topological amplification process is robust against disorder in the lattice parameters.

We study a circuit QED setup where multiple superconducting qubits are ultrastrongly coupled to a single radio-frequency resonator. In this extreme parameter regime of cavity QED the dynamics of the electromagnetic mode is very slow compared to all other relevant timescales and can be described as an effective particle moving in an adiabatic energy landscape defined by the qubits. The focus of this work is placed on settings with two or multiple qubits, where different types of symmetry-breaking transitions in the ground- and excited-state potentials can occur. Specifically, we show how the change in the level structure and the wave packet dynamics associated with these transition points can be probed via conventional excitation spectra and Ramsey measurements performed at GHz frequencies. More generally, this analysis demonstrates that state-of-the-art circuit QED systems can be used to access a whole range of particle-like quantum mechanical phenomena beyond the usual paradigm of coupled qubits and oscillators.

The discovery of topological materials has challenged our understanding of condensed matter physics and led to novel and unusual phenomena. This has motivated recent developments to export topological concepts into photonics to make light behave in exotic ways. Here, we predict several unconventional quantum optical phenomena that occur when quantum emitters interact with a topological waveguide QED bath, namely, the photonic analogue of the Su-Schrieffer-Hegger model. When the emitters frequency lies within the topological band-gap, a chiral bound state emerges, which is located at just one side (right or left) of the emitter. In the presence of several emitters, it mediates topological, long-range tunable interactions between them, that can give rise to exotic phases such as double N\’eel ordered states. On the contrary, when the emitters’ optical transition is resonant with the bands, we find unconventional scattering properties and different super/subradiant states depending on the band topology. We also investigate the case of a bath with open boundary conditions to understand the role of topological edge states. Finally, we propose several implementations where these phenomena can be observed with state-of-the-art technology.

We demonstrate that it is possible to implement a quantum perceptron with a sigmoid activation function as an efficient, reversible many-body unitary operation. When inserted in a neural network, the perceptron’s response is parameterized by the potential exerted by other neurons. We prove that such a quantum neural network is a universal approximator of continuous functions, with at least the same power as classical neural networks. While engineering general perceptrons is a challenging control problem –also defined in this work–, the ubiquitous sigmoid-response neuron can be implemented as a quasi-adiabatic passage with an Ising model. In this construct, the scaling of resources is favorable with respect to the total network size and is dominated by the number of layers. We expect that our sigmoid perceptron will have applications also in quantum sensing or variational estimation of many-body Hamiltonians.